Tim - the general guidance you need is provided in PG 1 -
Practice guide 1: first registrations - GOV.UK
The forms you refer to would be the correct ones to use and PG 1 explains which names are to be searched with Land Charges
One thing you need to confirm is did your Mother actually transfer the legal ownership to herself or did she just inherit thinking she was now the legal owner. Inheritance doesn't transfer the legal ownership so if she did nothing then the property still forms part of her Father's estate and that has to be dealt with/considered also
If you are transferring the ownership now then it is a compulsory, not voluntary, first registration