Hi Debbie - this is covered in a number of other threads on the forum re how to apply to split/sub divide a registered title
See
How to split a freehold title? · HM Land Registry for example
The type of split you refer to would happen naturally if you did sell part of the title so we will often refuse to split it without reasonable cause being proven. That decision would only be made once the application has been submitted as there can be other reason(s) as to why we might refuse also